Utilization of Black Tea Dregs as an Adsorbent of Metal Fe in Water using UV-Vis Spectrophotometry
DOI:
https://doi.org/10.22487/j24775185.2025.v14.i3.pp187-193Keywords:
Adsorption, black tea dregs, iron(III)Abstract
Tea dregs are household organic waste materials that can be utilized as low-cost adsorbents for heavy metal removal. Previous studies mainly employed green tea dregs and focused on Cu(II) adsorption, while studies on Fe(III) adsorption using black tea dregs and their direct application to Fe-contaminated water remain limited. This study evaluates the adsorption performance of black tea dregs toward Fe(III) ions and their application in water samples. Batch adsorption experiments were conducted using FeCl₃ solutions at pH 4.8 to determine the optimum contact time (15–90 minutes) and initial concentration (100–300 ppm). Fe(III) concentrations were analyzed using UV–Vis spectrophotometry. The results demonstrated an optimal contact time of 60 min and an optimal concentration, achieving 99.26% adsorption efficiency. Adsorption followed the Langmuir isotherm model with a maximum capacity of 37.04 mg/g (R² = 0.998). Application to well water samples resulted in 83.74% Fe removal, confirming the potential of black tea dregs as adsorbents.
References
Abduljabbar, T. N., Sharp, B. L., Reid, H. J., Barzegar-Befroeid, N., Peto, T., & Lengyel, I. (2019). Determination of Zn, Cu and Fe in human patients' serum using micro-sampling ICP-MS and sample dilution. Talanta, 204(May), 663-669. https://doi.org/10.1016/j.talanta.2019.05.098
Abed, E. A. M., Alaboudi, K. A. N., Abbas, M. H. H., Attia, T. M. S., & Abdelhafez, A. A. (2024). Iron contamination in groundwater: risk assessment and remediation techniques in Egypt’s new valley. Water, 16(13), 1834. https://doi.org/10.3390/w16131834
Agawijaya, R. G. M. I., Santoso, B., & Suryadi, J. (2021). Perbandingan efektivitas ampas teh hitam dan ampas teh hijau sebagai adsorben ion logam Cr (VI). Fullerene Journal of Chemistry, 6(2), 101–109. https://doi.org/10.37033/fjc.v6i2.327
Akbar, I. (2023). Pemanfaatan ampas teh kaskara sebagai adsorben penyerap logam besi (Fe) dengan pendekatan kinetika isoterm Freundlich dan Langmuir. Unpublished doctoral dissertation, Banda Aceh: UIN Ar Raniry Banda Aceh.
Ali, H., Khan, E., & Ilahi, I. (2019). Environmental chemistry and ecotoxicology of hazardous heavy metals: environmental persistence, toxicity, and bioaccumulation. Journal of Chemistry, 2019(1), 6730305. https://doi.org/10.1155/2019/6730305
Amran, M. B., Aminah, S., Rusli, H., & Buchari, B. (2020). Bentonite-based functional material as preconcentration system for determination of chromium species in water by flow injection analysis technique. Heliyon, 6(5), 1-7. https://doi.org/10.1016/j.heliyon.2020.e04051
Cheng, L., Yang, Q., Chen, Z., Zhang, J., Chen, Q., Wang, Y., & Wei, X. (2020). Distinct changes of metabolic profile and sensory quality during Qingzhuan tea processing revealed by LC-MS-based metabolomics. Journal of Agricultural and Food Chemistry, 68(17), 4955–4965. https://dx.doi.org/10.1021/acs.jafc.0c00581?ref=pdf
Cojocaru, V. C., Cristea, I. N., Paris, I. A., Ionescu, I. A., & Chiriac, F. L. (2024). Exploring sustainable solutions: Dynamic adsorption, isotherm models, and kinetics of organic contaminants on polystyrene microplastics. Sustainability, 16(17), 1-14. https://doi.org/10.3390/su16177743
Deng, Z., Yi, Z., Chen, G., Ma, X., Ya, T., & Li, X. (2020). Green tea polyphenol nanoparticle as a novel adsorbent to remove Pb²⁺ from wastewater. Materials Letters, 284(1), 128986. https://doi.org/10.1016/j.matlet.2020.128986
Duarah, P., Haldar, D., Singhania, R. R., Dong, C. D., Patel, A. K., & Purkait, M. K. (2024). Sustainable management of tea wastes: Resource recovery and conversion techniques. Critical Reviews in Biotechnology, 44(2), 255–274. https://doi.org/10.1080/07388551.2022.2157701
Edet, U. A., & Ifelebuegu, A. O. (2020). Kinetics, isotherms, and thermodynamic modeling of the adsorption of phosphates from model wastewater using recycled brick waste. Processes, 8(6), 1-15. https://doi.org/10.3390/pr8060665
Elewa, A. M., Amer, A. A., Attallah, M. F., Gad, H. A., Al-Ahmed, Z. A. M., & Ahmed, I. A. (2023). Chemically activated carbon based on biomass for adsorption of Fe(III) and Mn(II) ions from aqueous solution. Materials, 16(3), 1–21. https://doi.org/10.3390/ma16031251
Hamedi, H., Rezaei, N., & Zendehboudi, S. (2023). Investigation of emulsified oil adsorption onto functionalized magnetic nanoparticles—kinetic and isotherm models. Energies, 16(24), 1-15. https://doi.org/10.3390/en16248073
Imani, A., Sukwika, T., & Febrina, L. (2020). Karbon aktif ampas tebu sebagai adsorben penurun kadar besi dan mangan limbah air asam tambang. Jurnal Teknologi, 13(1), 33–42. https://dx.doi.org/10.24853/jurtek.13.1.33-42
Kardiman., Ifa, L., & Rasyid, R. (2019). Pembuatan adsorben dari sabut kelapa sebagai penyerap logam berat Pb (II). Iltek: Jurnal Teknologi, 14(2), 2083–2087. https://doi.org/10.47398/iltek.v14i2.421
Katadata Media Network. (2022). Katadata. Retrieved August 20, 2024, from http://databoks.katadata.co.id/
Khaliha, S., Jones, D., Kovtun, A., Navacchia, M. L., Zambianchi, M., Melucci, M., & Palermo, V. (2023). The removal efficiency of emerging organic contaminants, heavy metals and dyes: Intrinsic limits at low concentrations. Environmental Science: Water Research & Technology, 9(6), 1558–1565. https://doi.org/10.1039/D2EW00644H
Kwiatkowski, M. (2024). An analysis of the textural properties of activated carbons obtained from biomass via the LBET, NLDFT and QSDFT methods. Scientific Reports, 14(1), 26472. https://doi.org/10.1038/s41598-024-76297-x
Laili, N. N., Aji, M. P., & Sulhadi. (2017). Analisis sifat adsorpsi karbon aktif kayu dan tempurung kelapa pada limbah cair batik di kota Pekalongan. In Prosiding Seminar Nasional Fisika (pp. 87–92). Jakarta: Universitas Negeri Jakarta. https://doi.org/10.21009/03.SNF2017.02.MPS.14
Mamun, K. R., Saha, N. K., & Chakrabarty, S. (2019). A comparative study of the adsorption capacity of tea leaves and orange peel for the removal of Fe(III) ion from wastewater. Journal of Chemical Health Risks, 9(2), 107–115. https://doi.org/ 10.22034/jchr.2019.664496
Morita, N., Toma, Y., & Ueno, H. (2024). Acceleration of composting by addition of clinker to tea leaf compost. Waste, 2(1), 72–84. https://doi.org/10.3390/waste2010004
Nirmala., Tiwow, V. M. A., & Suherman. (2015). Adsorption of copper (Cu) and iron (Fe) ions using biocharcoal of plantain bark (Musa sapientum). Jurnal Akademika Kimia, 4(4), 189–196. https://doi.org/10.22487/j24775185.2015.v4.i4.7870
Nurmayanti, Y., Poba, D., Marpaung, M. E. (2022). Adsorption of Fe(III) ion in tablets Fe supplement by black tea dregs. Jurnal Akademika Kimia, 11(3), 197–201. https://doi.org/10.22487/j24775185.2022.v11.i3.pp197-201
Ozdes, D., Tilki, N., & Seker, S. (2022). Insights into brewed tea waste as a green and low-priced adsorbent for solid-phase extraction of Cd(II) ions: Isotherm, kinetic, and artificial neural network approach. Journal of Analytical Science and Technology, 13(50), 1-14. https://doi.org/10.1186/s40543-022-00360-3
Pratama, D. A. (2017). Efektivitas ampas teh sebagai adsorben alternatif logam Fe dan Cu pada air sungai Mahakam. Jurnal Integrasi Proses, 6(3), 131–138. https://dx.doi.org/10.36055/jip.v6i3.1560
Satyam, S., & Patra, S. (2024). Innovations and challenges in adsorption-based wastewater remediation: A comprehensive review. Heliyon, 10(9), 1-24. https://doi.org/10.1016/j.heliyon.2024.e29573
Wijayanti, A., Susatyo, E. B., Sukarjo, & Kurniawan, C. (2018). Adsorpsi logam Cr (VI) dan Cu (II) pada tanah dan pengaruh penambahan pupuk organik. Indonesian Journal of Chemical Science, 7(3), 242–248. https://doi.org/10.15294/ijcs.v2i2.1595
Yang, A. L., Yang, S. Y., & Zhu, Y. K. (2021). Magnetic modification of used tea leaves for uranium adsorption. New Carbon Materials, 36(4), 821-826. https://doi.org/10.1016/S1872-5805(21)60053-7
Zevi, Y., & Septiyani, E. (2020). Technology for iron and manganese ion removal from groundwater: A review. MATTER International Journal of Science and Technology, 6(2), 26–40. https://doi.org/10.20319/mijst.2020.62.2640
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 sauli safitri, Sitti Aminah, Yuli Nurmayanti, Sitti Rahmawati, Tri Santoso

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.










