Degradation of Natural Rubber as Asphalt Mixes Modifier using UV-Ozone Light

Authors

  • Irene I. C. Ritonga Universitas Sumatera Utara
  • Tamrin Tamrin Universitas Sumatera Utara
  • Marpongahtun Marpongahtun Universitas Sumatera Utara

DOI:

https://doi.org/10.22487/j24775185.2023.v12.i2.pp78-85

Keywords:

Asphalt, bitumen, natural rubber, photochemical, UV / ozone light, asphalt-rubber, nr degradation

Abstract

The elastic properties of natural rubber are indispensable in improving the physical properties of asphalt mixtures. However, the long natural rubber molecule chains make it difficult to modify with other polymeric materials, so it needs to be degraded. In this study, the authors succeeded in degrading natural rubber using a combination of UV light and ozone with the addition of an H2O2 initiator; from the FTIR data, it appears that there are peaks indicating vibrations of the C=O and –OH groups indicating that natural rubber chain termination has occurred. The addition of natural rubber to asphalt was carried out with several variations, namely 8; 10; 12; 14; 16 % (to asphalt content), from the results of the softening point and ductility test of the asphalt mixture explained that the addition of 12 % natural rubber was the most optimum mixture. This result explains that efforts to degrade natural rubber using the UV - ozone combination method can increase the optimum insertion of natural rubber into asphalt mixtures by up to 100 % from previous studies.

Author Biographies

Irene I. C. Ritonga, Universitas Sumatera Utara

Postgraduate Program of Chemistry

Tamrin Tamrin, Universitas Sumatera Utara

Postgraduate Program of Chemistry, Faculty of Mathematics and Natural ScienceDepartment of Chemistry, Faculty of Mathematics and Natural Science

Marpongahtun Marpongahtun, Universitas Sumatera Utara

Postgraduate Program of Chemistry, Faculty of Mathematics and Natural ScienceDepartment of Chemistry, Faculty of Mathematics and Natural Science

References

Azahar, N. B. M., Hassan, N. B. A., Jaya, R. P., Kadir, M. A. B. A., Yunus, N. Z. B. M., & Mahmud, M. Z. H. (2016). An overview on natural rubber application for asphalt modification. International Journal of Agriculture, Forestry and Plantation, 2(February), 212–218.

Azhar, N. H. A., Rasid, H. M., & Yusoff, S. F. M. (2016). Chemical modifications of liquid natural rubber. AIP Conference Proceedings (pp. 030024-1-030024-6). Malaysia: AIP Publishing.

Badan Standarisasi Nasional. (2011). SNI 2432-2011 cara uji daktilitas aspal. Jakarta: Badan Penerbit PU.

Badan Standarisasi Nasional. (2011). SNI 2434-2011 cara uji titik lembek aspal. Jakarta: Badan Penerbit PU.

Badan Standarisasi Nasional. (2015). SNI 8198-2015 spesifikasi campuran beraspal bergradasi menerus (laston). Jakarta: Badan Penerbit PU.

Bahruddin., Fadhillah, I., Septian., Wiranata, A., & Zahrina, I. (2020). Molecular weight of liquid natural rubber (LNR) product from the chemical depolymerization process of high molecular weight narutal rubber latex. Journal of Physics: Conference Series (pp. 1-5). United Kingdom: IOP Publishing.

Grumoorthy, T. A. (2013). Improving the ductility and elastic recovery of bitumen-natural rubber latex blend. Unpublished master’s thesis. Malaysia: Universiti Tunku Abdul Rahman.

Ibrahim, S., Othman, N., Sreekantan, S., Tan, K. S., Nor, Z. M., & Ismail, H. (2018). Preparation and characterization of low-molecular-weight natural rubber latex via photodegradation catalyzed by nano TiO2. Polymers, 10(11), 1-17.

Ibrahim, S., Othman, N., & Yusof, N. H. (2021). Preparation, characterization and properties of liquid natural rubber with low non-rubber content via photodegradation. Polymer Bulletin, 78(February), 559–575.

Kim, I., Lee, B., Sohn, K., Yoon, J., & Lee, J. (2016). Characterization of the UV oxidation of raw natural rubber thin film using image and FT-IR analysis. Elastromer and Composites, 51(1), 1–9.

Krishna, Y. B., Ramadhani., & Jimmyanto, H. (2023). Predicting stiffness asphalt natural rubber latex modulus value using multiple linear regression analysis. JCEBT (Journal of Civil Engineering, Building and Transportation), 7(1), 293-300.

Li, H., Cui, C., Temitope, A. A., Feng, Z., Zhao, G., & Guo, P. (2022). Effect of SBS and crumb rubber on asphalt modification : A review of the properties and practical application. Journal of Traffic and Transportation Engineering (English Edition), 9(5), 836–863.

McNally, T. (2011). Introduction to polymer modified bitumen (PmB). In T. McNally (Eds.), Polymer modified bitumen properties and characterisation (pp. 1-22). Cambridge: Woodhead Publishing.

Nivitha, M. R., Prasad, E., & Krishnan, J. M. (2016). Ageing in modified bitumen using FTIR spectroscopy. International Journal of Pavement Engineering, 17(7), 565–577.

Porto, M., Caputo, P., Loise, V., Eskandarsefat, S., Teltayev, B., & Rossi, C. O. (2019). Bitumen and bitumen modification: A review on latest advances. Applied Sciences, 9(4), 1-35.

Prastanto, H., Firdaus, Y., Puspitasari, S., Ramadhan, A., & Falaah, A. F. (2018). Sifat fisika aspal modifikasi karet alam pada berbagai jenis dan dosis lateks karet alam. Jurnal Penelitian Karet, 36(1), 65–76.

Rasool, R. T., Wang, S., Zhang, Y., Li, Y., & Zhang, G. (2017). Improving the aging resistance of SBS modified asphalt with the addition of highly reclaimed rubber. Construction and Building Materials, 145(August), 126–134.

Saleh, A. B. B., Ishak, Z. A. M., Hashim, A. S., Kamil, W. A., & Ishiaku, U. S. (2014). Synthesis and characterization of liquid natural rubber as impact modifier for epoxy resin. Physics Procedia, 55(August), 129–137.

Sani, A., Shariff, K. A., Hasan, M. R. M., Ando, T., & Imai, H. (2021). Behavioural interface-bonding and chemical characterization of silane and wax based additives on latex modified asphalt binders. International Journal of Adhesion and Adhesives, 106(April), 1-8.

Sheng, Y., Li, H., Geng, J., Tian, Y., Li, Z., & Xiong, R. (2017). Production and performance of desulfurized rubber asphalt binder. International Journal of Pavement Research and Technology, 10(3), 262–273.

Soares, F. A., & Steinbüchel, A. (2022). Natural rubber degradation products: Fine chemicals and reuse of rubber waste. European Polymer Journal, 165(February), 1-16.

Wen, Y., Wang, Y., Zhao, K., & Sumalee, A. (2015). The use of natural rubber latex as a renewable and sustainable modifier of asphalt binder. International Journal of Pavement Engineering, 18(6), 547-559.

Wisetkhamsai, K., Patthaveekongka, W., & Arayapranee, W. (2023). Study on degradation of natural rubber latex using hydrogen peroxide and sodium nitrite in the presence of formic acid. Polymers, 15(4), 1-16.

Zhang, C., Wang, H., You, Z., Gao, J., & Irfan, M. (2019). Performance test on styrene-butadiene-styrene (SBS) modified asphalt based on the different evaluation methods. Applied Sciences, 9(3), 1–11.

Zumrawi, M. M. E. (2017). Effect of crumb rubber modifiers (CRM) on characteristics of asphalt binders in Sudan. International Journal of Materials Science and Applications, 6(2-1). 1-6.

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Published

2023-05-31

How to Cite

Ritonga, I. I. C., Tamrin, T., & Marpongahtun, M. (2023). Degradation of Natural Rubber as Asphalt Mixes Modifier using UV-Ozone Light. Jurnal Akademika Kimia, 12(2), 78-85. https://doi.org/10.22487/j24775185.2023.v12.i2.pp78-85

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